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Novel titanocene derived from a partially alkylated s-indacene: Synthesis, characterization and comparative study with its zirconium analog

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Autor dc.contributor.author Oehninger L.
Autor dc.contributor.author Araneda J.F.
Autor dc.contributor.author Morales-Verdejo C.
Autor dc.contributor.author Munoz-Castro A.
Autor dc.contributor.author Mac-Leod Carey D.
Autor dc.contributor.author Adams C.
Autor dc.contributor.author Arratia-Perez R.
Autor dc.contributor.author Rojas R.
Autor dc.contributor.author Manriquez J.M.
Autor dc.contributor.author Chavez I.
Fecha Ingreso dc.date.accessioned 2014-04-05T00:02:28Z
Fecha Disponible dc.date.available 2014-04-05T00:02:28Z
Fecha en Repositorio dc.date.issued 2014-04-04
dc.identifier 10.1016/j.ica.2012.09.032
dc.description.abstract The preparation of a novel titanium(IV) metallocene (2), including 2,6-diethyl-4,8-dimethyl-5-hydroindacenide (Ic′H) as ligand was successfully achieved and it was characterized by means of 1H, 13C NMR and elemental analysis. Cyclic voltammetry studies were performed for complex 2 as well as for its zirconium analog 1. Both complexes were tested in the catalysis of ethylene polymerization, showing a considerable difference between their catalytic activities in a proportion of 625:1 between complex 1 and 2. DFT calculations were performed in order to gain further knowledge about the geometry of the complexes and their electronic properties and therefore explain the difference between their reactivity. © 2012 Elsevier B.V. All rights reserved. en_US
dc.source Inorganica Chimica Acta
Link Descarga dc.source.uri http://www.scopus.com/inward/record.url?eid=2-s2.0-84875240995&partnerID=40&md5=50ac32eddbc60214ce6801bc799e3124
Title dc.title Novel titanocene derived from a partially alkylated s-indacene: Synthesis, characterization and comparative study with its zirconium analog en_US
Tipo dc.type Article


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